BIODIESEL:  QUANTIFYING WATER AND FREE FATTY ACIDS IN WASTE VEGETABLE OIL TO IMPROVE THE YIELD OF FATTY ACID METHYL ESTERS IN THE TRANSESTERIFICATION PROCESS OF TRIGLYCERIDES.

 

Richard A. Smart

Bob Allen

Department of Physical Science

 

Alternative fuel sources are quickly becoming a topic of interest for many chemists.  The world’s oil supply is limited and a source of renewable fuel is greatly needed.  Biodiesel is a renewable fuel that is produced by the transesterification of triglycerides in vegetable oil.   The most economic feedstock to obtain is waste vegetable oil, which can be obtained from virtually any restaurant.

 

Biodiesel is the common term for Fatty Acid Methyl Esters (FAME’s).  These molecules are produced by the transesterification of triglyceride (lipid) molecules.  The process is carried out via a one step reaction in which methanol (MeOH) and potassium hydroxide (KOH) are combined to form potassium methoxide which catalyzes the transesterification process.  There are several factors that contribute to the yield and quality of biofuel produced from waste vegetable oil (WVO) that must be considered. 

 

Water present in the WVO can lead to the formation of a by-product known as alkali soap.  This can be reduced by quantifying the water in the WVO.  Also, the free fatty acids in the WVO play a major role in the ability of the reaction to go to completion.  A simple titration can be carried out and a correction for free fatty acids can be made that greatly increases the yield of Biodiesel. 

 

The main course of study throughout this research was improving methods of producing biodiesel yield and quality.  By quantifying Water and free fatty acid’s the yield of biodiesel has been increased.  Also, the elimination of alkali soap in the biodiesel has been accomplished by the addition of magnesium sulfate in the washing stage of production.

 

By improving the methods of biodiesel production and making this process known to the general public, it is hopeful that the process will soon become a household topic that will help reduce our dependence on fossil fuels.

 

 

 

 

 

 

 

MARKET AND PROFIT POINT IDENTIFICATION FOR BIODIESEL

 

Megan Judy and Crystal Washington

Loretta Cochran, Kim Troboy, and Bill Harmon

Department of Business and Economics

 

Current research on biodiesel business plans leads potential producers to consider a mid-range B100 biodiesel refinery in Arkansas unprofitable and unfeasible.   One flaw in these findings is a single source bias.  That is, each plan focused on having only one source for raw materials.  The following market research will center on a different approach – one where a refinery would take “yellow grease,” (made from used cooking oil), and also virgin soybean oil (with the beans crushed on site) to make B-100.  Blending and distribution would be outsourced to a local fuel distributor for sale as a B20 blend to local customers in Pope, Yell, and Johnson counties.  A business plan will be presented, resulting from this market research and the efforts of additional students in engineering and chemistry, which will include cost and capital considerations.  A local feasibility study will also be reviewed.